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Facile regiospecific intermolecular C–H insertion reactions of cyclic rhodium carbenoids have been achieved using diazo carbonyl compounds 1 and indole or N-substituted indoles to afford 1,3-dihydro-1′H-[3,3′]biindolyl-2-ones, 3ao in an excellent yield.

Graphical abstract: First example of regiospecific intermolecular C–H insertion reactions of cyclic rhodium carbenoids: novel synthesis of 3-indol-3′-yloxindoles

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