Issue 10, 2002

Competing Diels–Alder reactions of activated nitroethylene derivatives and [3,3]-sigmatropic rearrangements of the cycloadducts

Abstract

Diels–Alder reaction of nitroethylene derivatives with cyclohexa-1,3-diene afforded three pericyclic products some of which could be converted to others via a new [3,3]-sigmatropic rearrangement or via a Claisen rearrangement.

Graphical abstract: Competing Diels–Alder reactions of activated nitroethylene derivatives and [3,3]-sigmatropic rearrangements of the cycloadducts

Article information

Article type
Communication
Submitted
07 Jan 2002
Accepted
08 Apr 2002
First published
17 Apr 2002

Chem. Commun., 2002, 1090-1091

Competing Diels–Alder reactions of activated nitroethylene derivatives and [3,3]-sigmatropic rearrangements of the cycloadducts

P. A. Wade, J. K. Murray, S. Shah-Patel and H. T. Le, Chem. Commun., 2002, 1090 DOI: 10.1039/B200224H

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