Issue 6, 2002
From the journal:

Chemical Communications

Expression of the prohelicity of bis-cyclomanganated 2,3-diphenylquinoxaline through reactions with diaryldiazomethanes†

André de Cian,a   Jean-Pierre Djukic,*a   Jean Fischer,a   Michel Pfeffer*a  and  Karl Heinz Dötz*b  

* Corresponding authors

a UMR 7513 CNRS, Université Louis Pasteur, Strasbourg, France
E-mail: djukic@chimie.u-strasbg.fr; pfeffer@chimie.u-strasbg.fr

b Kekulé Institut für Organische Chemie und Biochemie der Universität Bonn, Gerhard-Domagk str. 1, Bonn, Germany
E-mail: doetz@uni-bonn.de

Abstract

The reactions of bis-cyclomanganated 2,3-diphenylquinoxaline with diazodiphenylmethane and 9-diazofluorene allowed the formation of a new oligomeric and dinuclear manganospiralene and the ready preparation of a pentacyclic helix comprising two (η5-fluorenyl)Mn(CO)3 fragments, whose helicity can be locked upon one-dimensional linear coordination to silver cation.

Graphical abstract: Expression of the prohelicity of bis-cyclomanganated 2,3-diphenylquinoxaline through reactions with diaryldiazomethanes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B111570G
Article type
Communication
Submitted
20 Dec 2001
Accepted
07 Feb 2002
First published
25 Feb 2002

Chem. Commun., 2002, 638-639

Permissions

Request permissions

Expression of the prohelicity of bis-cyclomanganated 2,3-diphenylquinoxaline through reactions with diaryldiazomethanes

A. de Cian, J. Djukic, J. Fischer, M. Pfeffer and K. H. Dötz, Chem. Commun., 2002, 638 DOI: 10.1039/B111570G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements