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Issue 6, 2002
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A highly efficient titanium-based olefin polymerisation catalyst with a monoanionic iminoimidazolidide π-donor ancillary ligand

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Abstract

The titanium complex Cp[1,3-(2′,6′-Me2C6H3)2(CH2N)2C[double bond, length as m-dash]N]Ti(CH2Ph)2, with a monoanionic η1-iminoimidazolidide ancillary ligand, is shown to be a highly efficient catalyst for olefin polymerisation when activated with the Lewis acid B(C6F5)3.

Graphical abstract: A highly efficient titanium-based olefin polymerisation catalyst with a monoanionic iminoimidazolidide π-donor ancillary ligand

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Article information


Submitted
12 Dec 2001
First published
25 Feb 2002

Chem. Commun., 2002, 608-609
Article type
Communication

A highly efficient titanium-based olefin polymerisation catalyst with a monoanionic iminoimidazolidide π-donor ancillary ligand

W. P. Kretschmer, C. Dijkhuis, A. Meetsma, B. Hessen and J. H. Teuben, Chem. Commun., 2002, 608 DOI: 10.1039/B111343G

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