Issue 5, 2002
From the journal:

Chemical Communications

The first perfluoroacetylacetonate metal complexes: as unexpectedly robust as tricky to make†

Viacheslav A. Petrov,*a   William J. Marshalla  and  Vladimir V. Grushin*a  

* Corresponding authors

a Central Research and Development, DuPont de Nemours & Co., Inc., Experimental Station, Wilmington, DE 19880-0328, USA
E-mail: viacheslav.a.petrov@usa.dupont.com; vlad.grushin-1@usa.dupont.com

Abstract

First metal complexes containing the perfluoroacetylacetonato ligand have been prepared by the reaction of anhydrous Ln(OAc)3 (Ln = Eu, Tb, Tm) with heptafluoroacetylacetone, optionally in the presence of other ligands Ph3PO, bpy, and PyO.

Graphical abstract: The first perfluoroacetylacetonate metal complexes: as unexpectedly robust as tricky to make

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Article information

DOI
https://doi.org/10.1039/B111249J
Article type
Communication
Submitted
10 Dec 2001
Accepted
29 Jan 2002
First published
13 Feb 2002

Chem. Commun., 2002, 520-521

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The first perfluoroacetylacetonate metal complexes: as unexpectedly robust as tricky to make

V. A. Petrov, W. J. Marshall and V. V. Grushin, Chem. Commun., 2002, 520 DOI: 10.1039/B111249J

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