Issue 6, 2002

Reaction of singlet oxygen with Ir(i) and Rh(i) thiolato complexes: oxidative addition vs. S-oxidation

Abstract

Singlet oxygen reacts with Ir(I) and Rh(I) thiolato complexes to form the corresponding Ir(III) and Rh(III) peroxo thiolato complexes which do not undergo intramolecular oxidation of the thiolate moiety.

Graphical abstract: Reaction of singlet oxygen with Ir(i) and Rh(i) thiolato complexes: oxidative addition vs. S-oxidation

Supplementary files

Article information

Article type
Communication
Submitted
13 Nov 2001
Accepted
12 Feb 2002
First published
27 Feb 2002

Chem. Commun., 2002, 570-571

Reaction of singlet oxygen with Ir(I) and Rh(I) thiolato complexes: oxidative addition vs. S-oxidation

D. G. Ho, R. Ismail, N. Franco, R. Gao, E. P. Leverich, I. Tsyba, N. N. Ho, R. Bau and M. Selke, Chem. Commun., 2002, 570 DOI: 10.1039/B110396M

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