Issue 6, 2002
From the journal:

Chemical Communications

Reaction of singlet oxygen with Ir(i) and Rh(i) thiolato complexes: oxidative addition vs. S-oxidation†

David G. Ho,a   Rehana Ismail,a   Nestor Franco,a   Ruomei Gao,a   Edward P. Leverich,a   Irina Tsyba,b   Nam Nhat Ho,b   Robert Baub  and  Matthias Selke*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, California State University, Los Angeles, Los Angeles, CA 90032, USA
E-mail: mselke@calstatela.edu

b Department of Chemistry, University of Southern California, Los Angeles, CA 90089, USA

Abstract

Singlet oxygen reacts with Ir(I) and Rh(I) thiolato complexes to form the corresponding Ir(III) and Rh(III) peroxo thiolato complexes which do not undergo intramolecular oxidation of the thiolate moiety.

Graphical abstract: Reaction of singlet oxygen with Ir(i) and Rh(i) thiolato complexes: oxidative addition vs. S-oxidation

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Article information

DOI
https://doi.org/10.1039/B110396M
Article type
Communication
Submitted
13 Nov 2001
Accepted
12 Feb 2002
First published
27 Feb 2002

Chem. Commun., 2002, 570-571

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Reaction of singlet oxygen with Ir(I) and Rh(I) thiolato complexes: oxidative addition vs. S-oxidation

D. G. Ho, R. Ismail, N. Franco, R. Gao, E. P. Leverich, I. Tsyba, N. N. Ho, R. Bau and M. Selke, Chem. Commun., 2002, 570 DOI: 10.1039/B110396M

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