Issue 4, 2002
From the journal:

Chemical Communications

Evidence that gold(iii) porphyrins are not electrochemically inert: facile generation of gold(ii) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

Karl M. Kadish,*ab   Wenbo E,a   Zhongping Ou,a   Jianguo Shao,a   Paul J. Sintic,b   Kei Ohkubo,c   Shunichi Fukuzumi*c  and  Maxwell J. Crossley*b  

* Corresponding authors

a Department of Chemistry, University of Houston, Houston, Texas, USA

b School of Chemistry, The University of Sydney, Australia
E-mail: m.crossley@chem.usyd.edu.au

c Department of Material and Life Science, Graduate School of Engineering, Osaka University, CREST, Japan Science and Technology Corporation (JST), Suita, Japan

Abstract

Gold(III) porphyrin 1 is shown to undergo reduction at the central metal ion to give the first known gold(II) porphyrin overturning the long held assumption that reduction of such complexes only occurs at the macrocycle.

Graphical abstract: Evidence that gold(iii) porphyrins are not electrochemically inert: facile generation of gold(ii) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

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Article information

DOI
https://doi.org/10.1039/B109795D
Article type
Communication
Submitted
26 Oct 2001
Accepted
03 Jan 2002
First published
29 Jan 2002

Chem. Commun., 2002, 356-357

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Evidence that gold(III) porphyrins are not electrochemically inert: facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

K. M. Kadish, W. E, Z. Ou, J. Shao, P. J. Sintic, K. Ohkubo, S. Fukuzumi and M. J. Crossley, Chem. Commun., 2002, 356 DOI: 10.1039/B109795D

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