Issue 3, 2002
From the journal:

Chemical Communications

Highly efficient use of NaOCl in the Ru-catalysed oxidation of aliphatic ethers to esters

Luca Gonsalvi,a   Isabel W. C. E. Arendsa  and  Roger A. Sheldon*a  

* Corresponding authors

a Laboratory for Organic Chemistry and Catalysis, Delft University of Technology, Julianalaan 136, Delft, The Netherlands
E-mail: R.A.Sheldon@tnw.tudelft.nl
Fax: +31 15 2781415
Tel: +31 15 2782675

Abstract

The selectivity of α-oxidation of ethers to esters via Ru–NaOCl can be dramatically improved by pH control, at high substrate to catalyst ratios using a stoichiometric amount of hypochlorite in biphasic media at room temperature.

Graphical abstract: Highly efficient use of NaOCl in the Ru-catalysed oxidation of aliphatic ethers to esters

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Article information

DOI
https://doi.org/10.1039/B109390H
Article type
Communication
Submitted
16 Oct 2001
Accepted
05 Dec 2001
First published
07 Jan 2002

Chem. Commun., 2002, 202-203

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Highly efficient use of NaOCl in the Ru-catalysed oxidation of aliphatic ethers to esters

L. Gonsalvi, I. W. C. E. Arends and R. A. Sheldon, Chem. Commun., 2002, 202 DOI: 10.1039/B109390H

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