Issue 1, 2002
From the journal:

Chemical Communications

Planar and central chiral [2.2]paracyclophane-based N,O-ligands as highly active catalysts in the diethylzinc addition to aldehydes†

Stefan Dahmena  and  Stefan Bräse*b  

* Corresponding authors

a Institut für Organische Chemie der Rheinisch-Westfälischen Technischen Hochschule Aachen, Professor-Pirlet-Strasse 1, D-52074, Aachen, Germany

b Kekulé-Institut für Organische Chemie und Biochemie der Rheinischen Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Strasse 1, D-53121, Bonn, Germany
E-mail: braese@uni-bonn.de
Fax: +49 228 739608
Tel: +49 228 732653

Abstract

The application of planar and central chiral [2.2]paracyclophane-based N,O-ligands in asymmetric diethylzinc additions to various aldehydes is described revealing an unusual substrate spectrum for the catalysts and their remarkably high activity.

Graphical abstract: Planar and central chiral [2.2]paracyclophane-based N,O-ligands as highly active catalysts in the diethylzinc addition to aldehydes

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Article information

DOI
https://doi.org/10.1039/B108347C
Article type
Communication
Submitted
17 Sep 2001
Accepted
11 Nov 2001
First published
29 Nov 2001

Chem. Commun., 2002, 26-27

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Planar and central chiral [2.2]paracyclophane-based N,O-ligands as highly active catalysts in the diethylzinc addition to aldehydes

S. Dahmen and S. Bräse, Chem. Commun., 2002, 26 DOI: 10.1039/B108347C

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