Issue 1, 2002
From the journal:

Chemical Communications

Ni(ii) N4-macrocycle grafted crown ether: caesium cobalt(iii) bis(dicarbollide) coordination polymer

Nino Malic,a   Peter J. Nicholsa  and  Colin L. Raston*b  

* Corresponding authors

a School of Chemistry, Monash University, Clayton, Melbourne, Australia

b School of Chemistry, University of Leeds, Leeds, UK
E-mail: C.L.Raston@chem.leeds.ac.uk

Abstract

A mixture of a Ni(TMTAA) grafted crown ether and Cs[Co(C2B9H11)2] in toluene–CH2Cl2 affords a 1∶1 complex, comprised of layers of infinite two-dimensional polymeric arrays separated by layers of the cobalticarborane anion which themselves form two B–H⋯Cs+ hydrogen interactions.

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Article information

DOI
https://doi.org/10.1039/B108162D
Article type
Communication
Submitted
07 Sep 2001
Accepted
06 Nov 2001
First published
13 Dec 2001

Chem. Commun., 2002, 16-17

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Ni(II) N4-macrocycle grafted crown ether: caesium cobalt(III) bis(dicarbollide) coordination polymer

N. Malic, P. J. Nichols and C. L. Raston, Chem. Commun., 2002, 16 DOI: 10.1039/B108162D

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