Carotenoids and related polyenes. Part 9. Total synthesis of thermozeaxanthin and thermocryptoxanthin and the stabilizing effect of thermozeaxanthin on liposomes

Yumiko Yamano; Yoshitsugu Sakai; Masayuki Hara; Masayoshi Ito

doi:10.1039/B204011P

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Carotenoids and related polyenes. Part 9.¹ Total synthesis of thermozeaxanthin and thermocryptoxanthin and the stabilizing effect of thermozeaxanthin on liposomes

Yumiko Yamano,^a Yoshitsugu Sakai,^a Masayuki Hara^b and Masayoshi Ito*^a

Author affiliations

* Corresponding authors

^a Kobe Pharmaceutical University, Motoyamakita-machi, Higashinada-ku, Kobe 658-8558, Japan

^b Research Institute for Advanced Science and Technology, Osaka Prefecture University, 1-2 Gakuen-cho, Sakai, Osaka 599-8570, Japan

Abstract

Thermozeaxanthin and thermocryptoxanthin are efficiently synthesized via β-selective glucosidation of (3R)-3-hydroxy-β-ionone 7, and the stabilizing effects of zeaxanthin 5, its glucoside 3 and thermozeaxanthin-15 1a on liposomes are also examined.

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Article information

DOI: https://doi.org/10.1039/B204011P
Article type: Paper
Submitted: 24 Apr 2002
Accepted: 01 Jul 2002
First published: 18 Jul 2002

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J. Chem. Soc., Perkin Trans. 1, 2002, 2006-2013

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Carotenoids and related polyenes. Part 9. Total synthesis of thermozeaxanthin and thermocryptoxanthin and the stabilizing effect of thermozeaxanthin on liposomes

Y. Yamano, Y. Sakai, M. Hara and M. Ito, J. Chem. Soc., Perkin Trans. 1, 2002, 2006 DOI: 10.1039/B204011P

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Journal of the Chemical Society, Perkin Transactions 1