Issue 3, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Organo-scandium and -yttrium complexes supported by a salicylaldiminato ligand

David J. H. Emslie,a   Warren E. Piers†*a  and  Robert MacDonaldb  

* Corresponding authors

a Department of Chemistry, University of Calgary, 2500 University Drive N. W., Calgary, Alberta, Canada
E-mail: wpiers@ucalgary.ca

b X-Ray Structure Laboratory, Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada

Abstract

Reaction of a salicylaldiminato ligand with M(CH2SiMe2Ph)3(THF)2 (M = Sc, Y) leads to diastereoselective formation of highly thermally stable L2MR complexes whose reactivity with dihydrogen to form Group 3 metal hydrides is described.

Graphical abstract: Organo-scandium and -yttrium complexes supported by a salicylaldiminato ligand

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Article information

DOI
https://doi.org/10.1039/B108336H
Article type
Communication
Submitted
13 Sep 2001
Accepted
06 Nov 2001
First published
04 Jan 2002

J. Chem. Soc., Dalton Trans., 2002, 293-294

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Organo-scandium and -yttrium complexes supported by a salicylaldiminato ligand

D. J. H. Emslie, W. E. Piers and R. MacDonald, J. Chem. Soc., Dalton Trans., 2002, 293 DOI: 10.1039/B108336H

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