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Issue 3, 2002
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Synthesis and characterization of self-assembled monolayers based on redox-active silane compounds on platinum surfaces

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Abstract

A novel alkanesilane (3-triethoxysilyl)propyl-carbamic acid 6-(9,10-dioxo-9,10-dihydro-anthracen-1-yloxy)-hexyl ester)(TESA), with a redox-active anthraquinone head group was shown to form self-assembled monolayers on a platinum oxide surface, without the use of a silane coupling agent. The TESA monolayers were characterized by X-ray electron spectroscopy (XPS), reflection–absorption infrared spectroscopy (IRRAS), and electrochemical methods.

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Article information


Submitted
06 Aug 2001
Accepted
19 Nov 2001
First published
19 Dec 2001

Phys. Chem. Chem. Phys., 2002,4, 522-526
Article type
Paper

Synthesis and characterization of self-assembled monolayers based on redox-active silane compounds on platinum surfaces

Y. Long, S. Herrwerth, W. Eck and M. Grunze, Phys. Chem. Chem. Phys., 2002, 4, 522
DOI: 10.1039/B107091F

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