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Issue 71, 2002

Anion exchange in co-ordination polymers: a solid-state or a solvent-mediated process?

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Abstract

Interconversion of chain co-ordination polymers {[Ag(4,4′-bipy)](X)} (X = NO3 or BF4) in aqueous media has been studied by IR and 1H NMR spectroscopy, transmission electron (TEM) and atomic force (AFM) microscopies and by X-ray powder diffraction (PXRD). The exchange leads to the formation of a pure crystalline phase of a new co-ordination polymer, and detailed TEM and AFM studies indicate a solvent-mediated rather than a solid-state mechanism for the exchange process.

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Article information


Submitted
04 Mar 2002
Accepted
01 May 2002
First published
19 Jul 2002

CrystEngComm, 2002,4, 426-431
Article type
Paper

Anion exchange in co-ordination polymers: a solid-state or a solvent-mediated process?

A. N. Khlobystov, N. R. Champness, C. J. Roberts, S. J.B. Tendler, C. Thompson and M. Schröder, CrystEngComm, 2002, 4, 426
DOI: 10.1039/B202217F

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