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Issue 24, 2002
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Functionalized heteropolyanions: high-valent metal nitrido fragments incorporated into a Keggin polyoxometalate structure

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Abstract

Three examples of nitrido-functionalized polyoxometalate species are reported, namely (n-Bu4N)4[PW11O39(OsN)] (1), (n-Bu4N)4[PW11O39(ReN)] (2), and (n-Bu4N)3[PW11O39(ReN)] (3), which feature the incorporation of [OsVI[triple bond, length as m-dash]N]3+, [ReVI[triple bond, length as m-dash]N]3+ and [ReVII[triple bond, length as m-dash]N]4+ fragments, respectively, into the framework of a Keggin-type heteropolyanion.

Graphical abstract: Functionalized heteropolyanions: high-valent metal nitrido fragments incorporated into a Keggin polyoxometalate structure

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Article information


Submitted
19 Sep 2002
Accepted
22 Oct 2002
First published
07 Nov 2002

Chem. Commun., 2002, 2970-2971
Article type
Communication

Functionalized heteropolyanions: high-valent metal nitrido fragments incorporated into a Keggin polyoxometalate structure

H. Kwen, S. Tomlinson, E. A. Maatta, C. Dablemont, R. Thouvenot, A. Proust and P. Gouzerh, Chem. Commun., 2002, 2970
DOI: 10.1039/B209173A

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