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Issue 6, 2002
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Palladium-catalyzed cyclization of alkenyl β-keto esters in the presence of chlorotrimethylsilane

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Abstract

PdCl2(CH3CN)2 catalyzed the cyclization of alkenyl β-keto esters in the presence of a stoichiometric amount of SiMe3Cl to form 2-carboalkoxycyclohexanones in good yield with excellent regioselectivity.

Graphical abstract: Palladium-catalyzed cyclization of alkenyl β-keto esters in the presence of chlorotrimethylsilane

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Supplementary files

Article information


Submitted
21 Dec 2001
Accepted
13 Feb 2002
First published
26 Feb 2002

Chem. Commun., 2002, 650-651
Article type
Communication

Palladium-catalyzed cyclization of alkenyl β-keto esters in the presence of chlorotrimethylsilane

T. Pei and R. A. Widenhoefer, Chem. Commun., 2002, 650
DOI: 10.1039/B111644D

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