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Issue 6, 2002
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Serendipitous syntheses and structures of [Cp2Nb(H){(SiMe2)2(μ-NR)}]

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The compound [Cp2Nb(SiMe2I)2H] reacts with H2NBut and HNEt2 to afford the unexpected imido-bridged 1,3-disilaniobocyclobutanes [Cp2Nb(H){(μ-SiR2)2NR}] (R = But (4), Et (5)) exhibiting surprising structural and spectral properties.

Graphical abstract: Serendipitous syntheses and structures of [Cp2Nb(H){(SiMe2)2(μ-NR)}]

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The article was received on 12 Dec 2001, accepted on 01 Feb 2002 and first published on 15 Feb 2002

Article type: Communication
DOI: 10.1039/B111636C
Chem. Commun., 2002, 568-569

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    Serendipitous syntheses and structures of [Cp2Nb(H){(SiMe2)2(μ-NR)}]

    G. I. Nikonov, S. F. Vyboishchikov, L. G. Kuzmina and J. A. K. Howard, Chem. Commun., 2002, 568
    DOI: 10.1039/B111636C

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