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Issue 8, 2002
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Vanadium nitride functionalization and denitrogenation by carbon disulfide and dioxide

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Abstract

A dramatic difference in behavior is observed for the dithiocarbamate and carbamate complexes [Ar(But)N]3V(NCE2)Na(THF)2 (E = S or O, respectively), prepared from the corresponding nitride species {[Ar(But)N]3V[triple bond, length as m-dash]NNa}2 by way of a nucleophilic addition reaction involving carbon disulfide or dioxide, and is rationalized with the aid of DFT calculations.

Graphical abstract: Vanadium nitride functionalization and denitrogenation by carbon disulfide and dioxide

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Article information


Submitted
12 Dec 2001
Accepted
06 Feb 2002
First published
26 Mar 2002

Chem. Commun., 2002, 902-903
Article type
Communication

Vanadium nitride functionalization and denitrogenation by carbon disulfide and dioxide

J. K. Brask, V. Durà-Vilà, P. L. Diaconescu and C. C. Cummins, Chem. Commun., 2002, 902
DOI: 10.1039/B111550M

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