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Issue 13, 2002
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The trimethylsilylation of acetylene

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Abstract

The gas-phase reaction of Me3Si+ ions with acetylene is remarkably sensitive to the environment, leading to substitution products in radiolytic systems at atmospheric pressure and to rearranged adduct ions in the FT-ICR cell at 10−8 Torr, while seeming unproductive in an intermediate pressure range.

Graphical abstract: The trimethylsilylation of acetylene

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Publication details

The article was received on 11 Apr 2002, accepted on 15 May 2002 and first published on 31 May 2002


Article type: Communication
DOI: 10.1039/B203587C
Chem. Commun., 2002, 1418-1419

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    The trimethylsilylation of acetylene

    B. Chiavarino, M. E. Crestoni and S. Fornarini, Chem. Commun., 2002, 1418
    DOI: 10.1039/B203587C

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