Chemical modification and blending of polymers in an extruder reactor

Abstract

Chemical modification and blending of polymers in an extruder reactor are discussed. Relationships between the parameters affecting the reaction kinetics, viz., mixing time, duration of a chemical reaction and the residence time of the system in the extruder reactor, and the structure of the materials produced are analysed. The mechanisms of (i) grafting of low-molecular-mass compounds onto polymers; (ii) reactions between terminal groups of different polymers and (iii) transesterification and interchange reactions are considered. The factors affecting the mechanism of dynamic vulcanisation and the properties of thermoplastic elastomers are identified. Solid-phase reactions of polysaccharides in an extruder are discussed. The priority aspects of studies on the chemical modification and blending of polymers are noted. The bibliography includes 90 references.