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Issue 9, 2001
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Low-temperature X-ray structural analysis of propanedinitrile derivatives substituted with a bis(4-dimethylaminophenyl)methyl group: the origin of elongation of the donor–acceptor substituted C–C bond

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Abstract

Push–pull type substitution at Csp3–Csp3 in the title compounds does not have special electronic effects on the bond length, and the observed expansion can be best accounted for by steric interaction between substituents.

Graphical abstract: Low-temperature X-ray structural analysis of propanedinitrile derivatives substituted with a bis(4-dimethylaminophenyl)methyl group: the origin of elongation of the donor–acceptor substituted C–C bond

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Supplementary files

Article information


Submitted
11 Apr 2001
Accepted
21 Jun 2001
First published
24 Jul 2001

J. Chem. Soc., Perkin Trans. 2, 2001, 1798-1801
Article type
Paper

Low-temperature X-ray structural analysis of propanedinitrile derivatives substituted with a bis(4-dimethylaminophenyl)methyl group: the origin of elongation of the donor–acceptor substituted C–C bond

T. Suzuki, K. Ono, H. Kawai and T. Tsuji, J. Chem. Soc., Perkin Trans. 2, 2001, 1798
DOI: 10.1039/B103269K

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