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Issue 21, 2001
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Synthesis of (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]benzene} chromium tricarbonyl via nucleophilic aromatic substitution of (η6-fluorobenzene) chromium tricarbonyl

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Abstract

Chiral hydroxylamine chromium tricarbonyl complexes may be prepared in satisfactory to reasonable yield via nucleophilic aromatic substitution of the anion derived from N,O-substituted hydroxylamines and (η6-fluorobenzene) chromium tricarbonyl. The enantiomerically pure complex (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]benzene} chromium tricarbonyl 6a was characterised by X-ray crystallography.

Graphical abstract: Synthesis of (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]benzene} chromium tricarbonyl via nucleophilic aromatic substitution of (η6-fluorobenzene) chromium tricarbonyl

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Article information


Submitted
09 Aug 2001
Accepted
20 Sep 2001
First published
12 Oct 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 2850-2855
Article type
Paper

Synthesis of (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]benzene} chromium tricarbonyl via nucleophilic aromatic substitution of (η6-fluorobenzene) chromium tricarbonyl

M. R. G. da Costa, M. J. M. Curto, S. G. Davies, J. Sanders and F. C. Teixeira, J. Chem. Soc., Perkin Trans. 1, 2001, 2850
DOI: 10.1039/B107237B

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