Issue 17, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Friedel–Crafts reactions of a sulfonyl-substituted vinylic epoxide with various aromatics

Svante Brandänge,*a   Jan-Erling Bäckvalla  and  Hans Leijonmarcka  

* Corresponding authors

a Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-l06 91 Stockholm, Sweden

Abstract

The phenylsulfonyl-substituted vinylic epoxide 1 was allowed to react with BF3·OEt2 and various aromatics. A highly regioselective but moderately stereoselective mono-Friedel–Crafts reaction occurred which led to products 2 (Table 1). The fluorine-containing compounds 3a–b and 4 were obtained as side products.

Graphical abstract: Friedel–Crafts reactions of a sulfonyl-substituted vinylic epoxide with various aromatics

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Article information

DOI
https://doi.org/10.1039/B103582G
Article type
Paper
Submitted
23 Apr 2001
Accepted
03 Jul 2001
First published
09 Aug 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 2051-2054

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Friedel–Crafts reactions of a sulfonyl-substituted vinylic epoxide with various aromatics

S. Brandänge, J. Bäckvall and H. Leijonmarck, J. Chem. Soc., Perkin Trans. 1, 2001, 2051 DOI: 10.1039/B103582G

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