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Issue 12, 2001
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Palladium catalysed elaboration of codeine and morphine

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Abstract

Palladium catalysed coupling reactions of 6-O-tert-butyldimethylsilyl-1-bromocodeine and 6-O-tert-butyldimethylsilyl-3-trifluoromethylsulfonylmorphine allow a range of substituted analogues of codeine in the 1-position and morphine in the 3-position to be efficiently and selectively prepared.

Graphical abstract: Palladium catalysed elaboration of codeine and morphine

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Article information


Submitted
20 Mar 2001
Accepted
03 May 2001
First published
22 May 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 1413-1420
Article type
Paper

Palladium catalysed elaboration of codeine and morphine

S. G. Davies, C. J. Goodwin, D. Pyatt and A. D. Smith, J. Chem. Soc., Perkin Trans. 1, 2001, 1413
DOI: 10.1039/B102581N

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