Issue 5, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Metabolites of the higher fungi. Part 32.1 Rosnecatrone, a phytotoxic bicyclo[4.1.0]hept-3-en-2-one from the fungus Rosellinia necatrix Prill

Raymond L. Edwards,*a   Derek J. Maitland,a   Ian J. Scowen,a   Antonio J. T. De Sousab  and  Anthony J. S. Whalleyc  

* Corresponding authors

a Department of Chemical and Forensic Sciences, School of Life Sciences, University of Bradford, Bradford, UK

b Departmento de Biologia e Nutricao de Fruteeiras, Apartado 158, Alcobaca, Portugal

c School of Biomolecular Sciences, Liverpool John Moores University, Byrom Street, Liverpool, UK

Abstract

Rosnecatrone 7 is a phytotoxic metabolite isolated from cultures of a virulent strain of the fungus Rosellinia necatrix. The compound is identified as 5-hydroxy-4-hydroxymethyl-1-(1-hydroxy-3-methylbut-2-enyl)-3-[(E )-propenyl]-7-oxabicyclo[4.1.0]hept-3-en-2-one by chemical and physical methods. The absolute configuration is determined and the X-ray structure of its borohydride reduced derivative, rosnecatrol 10 as the tetra-acetate is described.

Graphical abstract: Metabolites of the higher fungi. Part 32.1 Rosnecatrone, a phytotoxic bicyclo[4.1.0]hept-3-en-2-one from the fungus Rosellinia necatrix Prill

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B008195G
Article type
Paper
Submitted
11 Oct 2000
Accepted
17 Jan 2001
First published
08 Feb 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 537-542

Permissions

Request permissions

Metabolites of the higher fungi. Part 32. Rosnecatrone, a phytotoxic bicyclo[4.1.0]hept-3-en-2-one from the fungus Rosellinia necatrix Prill

R. L. Edwards, D. J. Maitland, I. J. Scowen, A. J. T. De Sousa and A. J. S. Whalley, J. Chem. Soc., Perkin Trans. 1, 2001, 537 DOI: 10.1039/B008195G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements