Issue 4, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Reactions involving fluoride ion. Part 47.1 Reactions of perfluorobicycloalkenes

Richard D. Chambers*a  and  Takayuki Nakamuraa  

* Corresponding authors

a Department of Chemistry, University of Durham, South Road, Durham, UK

Abstract

Electron deficient dienes 3 and 4 are obtained by defluorination of perfluorobicyclo-butylidene (1) and -pentylidene (2), using tetrakis(dimethylamino)ethene (TDAE), and these dienes are very reactive. With alkali metal fluorides, 4 gave a stable observable anion while 3 gave oligomers. The corresponding fluorinated allyl anion was however obtained via3 in the presence of TDAE. Further reactions of 3 and 4 are described.

Graphical abstract: Reactions involving fluoride ion. Part 47.1 Reactions of perfluorobicycloalkenes

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Article information

DOI
https://doi.org/10.1039/B007825P
Article type
Paper
Submitted
27 Sep 2000
Accepted
04 Dec 2000
First published
22 Jan 2001

J. Chem. Soc., Perkin Trans. 1, 2001, 398-406

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Reactions involving fluoride ion. Part 47. Reactions of perfluorobicycloalkenes

R. D. Chambers and T. Nakamura, J. Chem. Soc., Perkin Trans. 1, 2001, 398 DOI: 10.1039/B007825P

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