First example of a ic-dioxime and its homo- and heteropentanuclear complexes containing a macrobicyclic moiety

Abstract

The novel N,N′-substituted diaminoglyoxime (H₂L) containing a diazadioxadithiacyclo macrobicycle has been synthesized from an aromatic primary amine containing a cryptand unit and (E,E)-dichloroglyoxime. The homopentanuclear nickel(II) and heteropentanuclear complexes of dioxime were obtained.