Issue 4, 2001

An unusual Bamford-Stevens reaction of 17-toluenesulfonylhydrazono- 3β-acetoxy-14α-hydroxyandrost-5-ene

Abstract

The Bamford-Stevens reaction of 17-toluenesulfonylhydrazono-3β-acetoxy-14α-hydroxyandrost-5-ene was found to proceed with migration of the 18-methyl group and formation of a 13,14-epoxide.

Article information

Article type
Paper

Mendeleev Commun., 2001,11, 144-145

An unusual Bamford-Stevens reaction of 17-toluenesulfonylhydrazono- 3β-acetoxy-14α-hydroxyandrost-5-ene

V. V. Khripach, V. N. Zhabinskii, A. I. Kotyatkina, G. P. Fando, A. S. Lyakhov, A. A. Govorova, J. van der Louw, M. B. Groen and A. de Groot, Mendeleev Commun., 2001, 11, 144 DOI: 10.1070/MC2001v011n04ABEH001448

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