Issue 3, 2001
From the journal:

Mendeleev Communications

Kinetic and thermodynamic control in the synthesis of methylglyoxal thioacetals from 2-ethoxypropenal

Nataliya A. Keiko,   Evgeniya A. Funtikova,   Lyudmila G. Stepanova,   Yurii A. Chuvashev,   Lyudmila I. Larina  and  Mikhail G. Voronkov  

Abstract

Under kinetically controlled conditions, the addition of organylthiols to 2-ethoxypropenal follows the Markovnikov rule to give 2-ethoxy-2-organylthiopropanals which spontaneously isomerize to 1-ethoxy-1-organylthiopropanones in storage or in the presence of an acid catalyst.

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Article information

DOI
https://doi.org/10.1070/MC2001v011n03ABEH001415
Article type
Paper

Mendeleev Commun., 2001,11, 110-112

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Kinetic and thermodynamic control in the synthesis of methylglyoxal thioacetals from 2-ethoxypropenal

N. A. Keiko, E. A. Funtikova, L. G. Stepanova, Y. A. Chuvashev, L. I. Larina and M. G. Voronkov, Mendeleev Commun., 2001, 11, 110 DOI: 10.1070/MC2001v011n03ABEH001415

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