Abstract
The : a = 7.799(2), b = 9.212(1), c = 10.784(2) Å, α = 107.595(3), β = 92.877(3), γ = 110.248(3)°, V = 682.4(2) Å3
and Z = 2 for 1, and a = 7.694(1), b = 9.210(1), c = 10.764(2) Å, α = 108.598(3), β = 92.300(3), γ = 109.814(3)°, V = 670.6(2) Å3 and Z = 2 for 2. They consist of trinuclear motifs of pseudo-octahedral MO6 linked through μ-OH2 and μ-carboxylate to generate one-dimensional chains, which are further bridged by the tricarboxylate to form a non-interpenetrated three-dimensional network. The network possesses extended channels along all three crystallographic axes in which
- This article is part of the themed collection: Metal-organic conductors (enriched issue)