Issue 15, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Diastereoselective C–H bond activation of diisopropylamine at a hydridotris(pyrazolyl)borato rhodium fragment

Emmanuelle Teuma,a   François Malbosc,a   Vincent Pons,a   Carole Serra-Le Berre,a   Joël Jaud,b   Michel Etienne*c  and  Philippe Kalck*a  

* Corresponding authors

a Laboratoire de Catalyse et Chimie Fine, Ecole Nationale Supérieure de Chimie de Toulouse, Institut National Polytechnique, 31077 Toulouse cedex 4, France

b CEMES-CNRS, 29 Rue Jeanne Marvig, 31055 Toulouse cedex 4, France

c Laboratoire de Chimie de Coordination du CNRS, UPR 8241, 205 Route de Narbonne, 31077 Toulouse cedex 4, France

Abstract

Irradiation of [TpMe2,ClRh(CO)2] [TpMe2,Cl = hydridotris(4-chloro-3,5-dimethylpyrazolyl)borate] in diisopropylamine yields the C–H activated metallacycle [TpMe2,Cl[upper bond 1 start]RhH{CH2CH(CH3)N[upper bond 1 end]HiPr}] as a single diastereomer.

Graphical abstract: Diastereoselective C–H bond activation of diisopropylamine at a hydridotris(pyrazolyl)borato rhodium fragment

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Article information

DOI
https://doi.org/10.1039/B105327M
Article type
Communication
Submitted
18 Jun 2001
Accepted
21 Jun 2001
First published
16 Jul 2001

J. Chem. Soc., Dalton Trans., 2001, 2225-2227

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Diastereoselective C–H bond activation of diisopropylamine at a hydridotris(pyrazolyl)borato rhodium fragment

E. Teuma, F. Malbosc, V. Pons, C. Serra-Le Berre, J. Jaud, M. Etienne and P. Kalck, J. Chem. Soc., Dalton Trans., 2001, 2225 DOI: 10.1039/B105327M

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