Issue 15, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Folding of a poly(oxyethylene) chain as probed by photoinduced energy transfer between Ru– and Os–polypyridine termini

Simon J. A. Pope,a   Craig R. Rice,a   Michael D. Ward,*a   Angeles Farran Morales,b   Gianluca Accorsi,b   Nicola Armarolib  and  Francesco Barigelletti*b  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK
E-mail: mike.ward@bristol.ac.uk

b Istituto FRAE-CNR, Via P. Gobetti 101, Bologna, Italy
E-mail: franz@frae.bo.cnr.it

Abstract

The extent of photoinduced energy-transfer between [Ru(bipy)3]2+ and [Os(bipy)3]2+ units attached to either end of a deca(oxoethylene) 33-atom chain can be used to show how the distribution of end-to-end distances in the ensemble of conformations changes in different solvents.

Graphical abstract: Folding of a poly(oxyethylene) chain as probed by photoinduced energy transfer between Ru– and Os–polypyridine termini

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Article information

DOI
https://doi.org/10.1039/B104637N
Article type
Communication
Submitted
29 May 2001
Accepted
22 Jun 2001
First published
06 Jul 2001

J. Chem. Soc., Dalton Trans., 2001, 2228-2231

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Folding of a poly(oxyethylene) chain as probed by photoinduced energy transfer between Ru– and Os–polypyridine termini

S. J. A. Pope, C. R. Rice, M. D. Ward, A. F. Morales, G. Accorsi, N. Armaroli and F. Barigelletti, J. Chem. Soc., Dalton Trans., 2001, 2228 DOI: 10.1039/B104637N

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