Issue 8, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Tuning the metal-based redox potentials of manganese cis,cis-1,3,5-triaminocyclohexane complexes

Elizabeth A. Lewis,a   John R. Lindsay Smith,*a   Paul H. Walton,*a   Stephen J. Archibald,a   Simon P. Foxona  and  Gerard M. P. Giblinb  

* Corresponding authors

a Department of Chemistry, University of York, York, Heslington, UK

b Medicinal Chemistry, Glaxo Wellcome Research and Development, Gunnels Wood Road, Stevenage, Herts, UK

Abstract

A selection of 5-substituted salicylaldehydes have been reacted with cis,cis-triaminocyclohexane to prepare a series of tri-imine and tri-amine ligands; cyclic voltammetry has been used to show that the electronic effect of the substituent has a marked and systematic effect on the MnIII/MnIV and MnIII/MnII redox potentials of their manganese complexes.

Graphical abstract: Tuning the metal-based redox potentials of manganese cis,cis-1,3,5-triaminocyclohexane complexes

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Article information

DOI
https://doi.org/10.1039/B102103F
Article type
Communication
Submitted
06 Mar 2001
Accepted
15 Mar 2001
First published
29 Mar 2001

J. Chem. Soc., Dalton Trans., 2001, 1159-1161

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Tuning the metal-based redox potentials of manganese cis,cis-1,3,5-triaminocyclohexane complexes

E. A. Lewis, J. R. Lindsay Smith, P. H. Walton, S. J. Archibald, S. P. Foxon and G. M. P. Giblin, J. Chem. Soc., Dalton Trans., 2001, 1159 DOI: 10.1039/B102103F

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