Issue 10, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Unexpected reduction of vanadium(IV) to vanadium(III) in the presence of the chelate ligands2,2′-bipyridine (bpy) and 1,8-hydroxyquinoline (Hquin)

Manolis J. Manos,a   Anastasios J. Tasiopoulos,a   Catherine Raptopoulou,b   Aris Terzis,b   J. Derek Woollins,c   Alexandra M. Z. Slawin,c   Anastasios D. Keramidasd  and  Themistoklis A. Kabanos*a  

* Corresponding authors

a Department of Chemistry, Section of Inorganic and Analytical Chemistry, University of Ioannina, Ioannina, Greece
E-mail: tkampano@cc.uoi.gr

b NCPS Demokritos, Institute of Material Science, Agia Paraskevi, Attiki, Greece

c Department of Chemistry, University of St. Andrews, St. Andrews, Fife, UK

d Department of Chemistry, University of Cyprus, Nicosia, Cyprus

Abstract

The structures, NMR spectra and electrochemical properties of the vanadium(III) compounds, cis-[VIIICl2(acac)(bpy)] and [VIII(quin)3]·2CH3OH, formed from [VIVCl2(acac)2]·0.25CH2Cl2 (Hacac = pentane-2,4-dione) and [VIVOCl2(thf )2] with bpy and Hquin respectively are described as well as the structure of the catecholate dioxovanadium(V) dimer [Et3NH]2[VO2(μ-dtbc)]2 (H2dtbc = 3,5-di-tert-butylcatechol).

Graphical abstract: Unexpected reduction of vanadium(IV) to vanadium(III) in the presence of the chelate ligands 2,2′-bipyridine (bpy) and 1,8-hydroxyquinoline (Hquin)

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B102095L
Article type
Communication
Submitted
06 Mar 2001
Accepted
30 Mar 2001
First published
20 Apr 2001

J. Chem. Soc., Dalton Trans., 2001, 1556-1558

Permissions

Request permissions

Unexpected reduction of vanadium(IV) to vanadium(III) in the presence of the chelate ligands 2,2′-bipyridine (bpy) and 1,8-hydroxyquinoline (Hquin)

M. J. Manos, A. J. Tasiopoulos, C. Raptopoulou, A. Terzis, J. D. Woollins, A. M. Z. Slawin, A. D. Keramidas and T. A. Kabanos, J. Chem. Soc., Dalton Trans., 2001, 1556 DOI: 10.1039/B102095L

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements