Issue 13, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Acetylacetonatodifluorooxometalates of vanadium and molybdenum: syntheses and crystal structures

Andreas Stasch,a   Mark Schormann,a   Jörg Prust,a   Herbert W. Roesky,*a   Hans-Georg Schmidta  and  Mathias Noltemeyera  

* Corresponding authors

a Institut für Anorganische Chemie der Georg-August, Universität Göttingen, Tammannstr. 4, Göttingen, Germany
E-mail: hroesky@gwdg.de

Abstract

[Et4N][HF2] reacted with VO(acac)2 and MoO2(acac)2 in acetonitrile at room temperature with elimination of Hacac to produce the metalates [Et4N][(acac)VOF2] 1 and [Et4N][(acac)MoO2F2] 2, respectively. These compounds are the first examples of fluorometalates of vanadium and molybdenum bearing the acetylacetonato group. The crystal structures have been determined.

Graphical abstract: Acetylacetonatodifluorooxometalates of vanadium and molybdenum: syntheses and crystal structures

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Article information

DOI
https://doi.org/10.1039/B100740H
Article type
Paper
Submitted
22 Jan 2001
Accepted
15 May 2001
First published
12 Jun 2001

J. Chem. Soc., Dalton Trans., 2001, 1945-1947

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Acetylacetonatodifluorooxometalates of vanadium and molybdenum: syntheses and crystal structures

A. Stasch, M. Schormann, J. Prust, H. W. Roesky, H. Schmidt and M. Noltemeyer, J. Chem. Soc., Dalton Trans., 2001, 1945 DOI: 10.1039/B100740H

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