The solid superacid of BCl3/silica–alumina type was studied. It was found that a suitable carrier for superacid synthesis with BCl3 vapours should possess OH groups with strong acid properties situated in the proximity of strong Lewis centres. Superacid Brönsted centres are formed as a result of the reaction between adjacent OH groups (at least one of which should be of high acid strength) of the carrier and BCl3.
M. Marczewski, M. Dȩbowiak and H. Marczewska, Phys. Chem. Chem. Phys., 2001, 3, 1103 DOI: 10.1039/B009256H
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