Issue 47, 2001
From the journal:

CrystEngComm

Rico E. Del Sesto,a   Roger D. Sommerb  and  Joel S. Miller*a  

* Corresponding authors

a Department of Chemistry, University of Utah, 315 So. 1400 E. Rm. 2124, Salt Lake City, UT, USA
E-mail: jsmiller@chemistry.utah.edu

b Department of Chemistry, Colorado State University, Fort Collins, CO, USA

Abstract

The reaction of [Et4N]I and tetracyanoethylene (TCNE) forms [Et4N]2[TCNE]2, which possesses [TCNE]22− with a 2.827(3) Å intradimer CC bond distance and exhibits νC[triple bond, length half m-dash]N at 2191, 2170 and 2163 cm−1, νC[double bond, length half m-dash]C at 1365 cm−1, and UV-Vis bands at 26 150 and 16 850 cm−1.

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Article information

DOI
https://doi.org/10.1039/B108455K
Article type
Paper
Submitted
18 Sep 2001
Accepted
16 Oct 2001

CrystEngComm, 2001,3, 222-224

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[Et4N]2[TCNE]2 (TCNE = tetracyanoethylene) – an example of an exceptionally long 2.827 Å CC bond

R. E. Del Sesto, R. D. Sommer and J. S. Miller, CrystEngComm, 2001, 3, 222 DOI: 10.1039/B108455K

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