Issue 52, 2001
From the journal:

CrystEngComm

Kozo Shitagami,a   Tomoyuki Akutagawa,abc   Tatsuo Hasegawa,ab   Takayoshi Nakamura*ab  and  Neil Robertsond  

* Corresponding authors

a Graduate School of Environmental Earth Science, Hokkaido University, Sapporo 060-0810, Japan

b Research Institute for Electronic Science, Hokkaido University, Sapporo 060-0810, Japan
E-mail: tnaka@imd.es.hokudai.ac.jp

c PRESTO, Japan Science and Technology Corporation (JST), Japan

d Department of Chemistry, University of Edinburgh, Edinburgh, UK

Abstract

K(dibenzo-18-crown-6)[M(dmit)2](CH3CN)2 (M = Ni, Au), which have a one-dimensional supramolecular array, have been prepared. These salts are isomorphous and each K+(dibenzo-18-crown-6) suparamolecular cation unit is connected through the interaction of two CH3CN molecules. The [Ni(dmit)2]− molecules exist as isolated monomers, and the magnetic susceptibility of the salt exhibits Curie-type behavior.

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Article information

DOI
https://doi.org/10.1039/B107858E
Article type
Paper
Submitted
31 Aug 2001
Accepted
15 Nov 2001

CrystEngComm, 2001,3, 255-257

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An infinite supramolecular array structure in metal dithiolate complexes: crystal structure of K(dibenzo-18-crown-6)[M(dmit)2](CH3CN)2 (M = Ni, Au)

K. Shitagami, T. Akutagawa, T. Hasegawa, T. Nakamura and N. Robertson, CrystEngComm, 2001, 3, 255 DOI: 10.1039/B107858E

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