Issue 13, 2001
From the journal:

CrystEngComm

Eringathodi Suresh*a  and  Mohan Madhav Bhadbhade*b  

* Corresponding authors

a Silicates and Catalysis Discipline, Central Salt and Marine Chemicals Research Institute, G.B.Marg, Gujarat, India
E-mail: salt@csir.res.in

b National Chemical Laboratory, Physical Chemistry Division, India
E-mail: mohanb@sil.ncl.res.in

Abstract

The one-dimensional cavity-containing cationic complex [Co(bpe)2(H2O)2](ClO4)2·(H2O)2 is synthesized and characterized. Single crystal analysis reveals that the metal centres are doubly bridged via bpe ligands (bpe⊕=⊕1,2-bis(4-pyridyl)ethane) creating cationic channels with dimensions 9.29⊕×⊕9.94 Å across Co–Co(1) and C(6)–C(6A) atoms respectively, which are occupied by perchlorate anions and lattice water molecules along the c axis. The linear 1D polymeric chains run along the b axis and the versatile bpe ligand bridges the metal centres in a syn conformation.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B009706N
Article type
Paper
Submitted
04 Dec 2000
Accepted
06 Feb 2001

CrystEngComm, 2001,3, 50-52

Permissions

Request permissions

Metal–organic supramolecular architecture containing cationic cavities: synthesis and single crystal investigation of {[Co(bpe)2(H2O)2](ClO4)2·(H2O)2}n

E. Suresh and M. M. Bhadbhade, CrystEngComm, 2001, 3, 50 DOI: 10.1039/B009706N

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements