Issue 8, 2001
From the journal:

CrystEngComm

Stuart R. Batten,*ab   Bernard F. Hoskins,a   Boujemaa Moubaraki,b   Keith S. Murrayb  and  Richard Robsona  

* Corresponding authors

a School of Chemistry, University of Melbourne, Parkville, Victoria, Australia

b School of Chemistry, PO Box 23, Monash University, Australia
E-mail: stuart.batten@sci.monash.edu.au

Abstract

One-dimensional coordination polymer chains of M(tcm)2(H2O)2 (M⊕=⊕Co, Ni; tcm⊕=⊕tricyanomethanide, C(CN)3−, Me4pyz⊕=⊕tetramethylpyrazine) are linked into 3D networks by hydrogen bonding between the chains and the intercalated Me4pyz molecules, and between the chains themselves. Very weak magnetic coupling is observed for the high-spin d7 and d8 ions with no evidence of long-range order.

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Article information

DOI
https://doi.org/10.1039/B009438M
Article type
Paper
Submitted
24 Nov 2000
Accepted
18 Jan 2001

CrystEngComm, 2001,3, 33-35

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3D networks constructed using both coordinative and hydrogen bonding: synthesis, structure and magnetic properties of M(tcm)2(H2O)2·Me4pyz, M⊕=⊕Co, Ni

S. R. Batten, B. F. Hoskins, B. Moubaraki, K. S. Murray and R. Robson, CrystEngComm, 2001, 3, 33 DOI: 10.1039/B009438M

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