Issue 24, 2001

Chiral phosphite–phosphoroamidites: a new class of ligand for asymmetric catalytic hydrogenation

Abstract

A series of novel phosphite–phosphoroamidite ligands, derived from readily available D-xylose, has been used for the first time in the asymmetric Rh-catalyzed hydrogenation of a series of α,β-unsaturated carboxylic acid derivatives with excellent enantioselectivity (ee up to >99%).

Article information

Article type
Communication
Submitted
05 Oct 2001
Accepted
09 Nov 2001
First published
06 Dec 2001

Chem. Commun., 2001, 2702-2703

Chiral phosphite–phosphoroamidites: a new class of ligand for asymmetric catalytic hydrogenation

M. Diéguez, A. Ruiz and C. Claver, Chem. Commun., 2001, 2702 DOI: 10.1039/B109043G

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