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Issue 23, 2001
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The first example of a diazaarsolyl anion: structure and coordination

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Abstract

The first example of an aromatic diazaarsolyl anion 1 has been synthesised and structurally characterised; the X-ray crystal structure of 1 exhibits planar metallacyclic fragments which link together to generate a coordination polymer via bridging lithium cations.

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Article information


Submitted
25 Sep 2001
Accepted
23 Oct 2001
First published
15 Nov 2001

Chem. Commun., 2001, 2480-2481
Article type
Communication

The first example of a diazaarsolyl anion: structure and coordination polymerisation of the aromatic metallacycle benzo[1,3,2]diazaarsolyl lithium·2THF

M. A. Paver, J. S. Joy and M. B. Hursthouse, Chem. Commun., 2001, 2480
DOI: 10.1039/B108593J

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