Issue 22, 2001

Chelating alkoxy-N-heterocyclic carbene complexes of silver and copperElectronic supplementary information (ESI) available: spectroscopic data for 13, cyclic voltammetry. See http://www.rsc.org/suppdata/cc/b1/b107855k/

Abstract

Incorporation of an alkoxide functional group into an N-heterocyclic carbene (NHC) ligand allows the synthesis of the first anionic NHC chelating ligands, which react to give the first neutral, molecular silver(I) alkoxide carbene complex, and a copper(I) derivative containing the first non-macrocyclic, square planar Cu(I) centres.

Graphical abstract: Chelating alkoxy-N-heterocyclic carbene complexes of silver and copper

Supplementary files

Article information

Article type
Communication
Submitted
31 Aug 2001
Accepted
27 Sep 2001
First published
22 Oct 2001

Chem. Commun., 2001, 2340-2341

Chelating alkoxy-N-heterocyclic carbene complexes of silver and copper

P. L. Arnold, A. C. Scarisbrick, A. J. Blake and C. Wilson, Chem. Commun., 2001, 2340 DOI: 10.1039/B107855K

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