The synthesis and aminohydroxylation of a series of acyclic
allylic carbamates is described: the formation of a putative
O![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
OsNR linkage between the transition metal and substrate is
proposed to account for the high levels of regioselectivity that were
observed; proof of the structure of one of the aminohydroxylation products
was obtained through X-ray crystallography.
The regioselective aminohydroxylation of allylic carbamates
T. J. Donohoe, P. D. Johnson, M. Helliwell and M. Keenan, Chem. Commun., 2001, 2078 DOI: 10.1039/B107253F
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