Issue 22, 2001
From the journal:

Chemical Communications

A novel intramolecular through-space interaction between F and CN: a strategy for the conformational control of an acyclic system†

Kiyoharu Nishide,*a   Yuri Hagimoto,a   Hiroaki Hasegawa,a   Motoo Shiro‡b  and  Manabu Node*a  

* Corresponding authors

a Department of Pharmaceutical Manufacturing Chemistry, Kyoto Pharmaceutical University, Misasagi, Yamashina, Kyoto, Japan.
E-mail: node@mb.kyoto-phu.ac.jp;
Fax: +81-75-595-4775;
Tel: +81-75-595-4639

b Rigaku Corporation, 3-9-12 Matsubara, Akishima, Tokyo, Japan

Abstract

X-Ray crystallographic analyses of fluorocyanides anti-1 and 2 revealed a novel intramolecular through-space interaction between F and CN in an acyclic system, which was applied to a stereoselective protonation of acyclic fluorocyanides 2 having flexible conformation.

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Article information

DOI
https://doi.org/10.1039/B107213G
Article type
Communication
Submitted
08 Aug 2001
Accepted
11 Oct 2001
First published
02 Nov 2001

Chem. Commun., 2001, 2394-2395

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A novel intramolecular through-space interaction between F and CN: a strategy for the conformational control of an acyclic system

K. Nishide, Y. Hagimoto, H. Hasegawa, M. Shiro and M. Node, Chem. Commun., 2001, 2394 DOI: 10.1039/B107213G

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