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Issue 22, 2001
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Ruthenium-catalysed asymmetric hydrosilylation of ketoximes using chiral oxazolinylferrocenylphosphines

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Abstract

Chiral ruthenium(II) complexes, RuCl2(PPh3)(oxazolinylferrocenylphosphine), have been found to be effective catalysts for asymmetric hydrosilylation of ketoximes to give the corresponding primary amines in good yields with high enantioselectivities (up to 89% ee) after acid hydrolysis.

Graphical abstract: Ruthenium-catalysed asymmetric hydrosilylation of ketoximes using chiral oxazolinylferrocenylphosphines

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Publication details

The article was received on 19 Jul 2001, accepted on 10 Oct 2001 and first published on 26 Oct 2001


Article type: Communication
DOI: 10.1039/B106435P
Citation: Chem. Commun., 2001,0, 2360-2361
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    Ruthenium-catalysed asymmetric hydrosilylation of ketoximes using chiral oxazolinylferrocenylphosphines

    I. Takei, Y. Nishibayashi, Y. Ishii, Y. Mizobe, S. Uemura and M. Hidai, Chem. Commun., 2001, 0, 2360
    DOI: 10.1039/B106435P

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