Jump to main content
Jump to site search

Issue 19, 2001
Previous Article Next Article

The first observation of the [Cp3Mn] anion; structures of hexagonal [(η2-Cp)3MnK·1.5thf] and ion-separated [(η2-Cp)3Mn]2[Mg(thf)6] ·2thfElectronic supplementary information (ESI) available: experimental details and figure of the static disordering arising from superimposition of the two types of sheet of 1. See http://www.rsc.org/suppdata/cc/b1/b106366a/

Author affiliations

Abstract

Hexagonal [(η2-Cp)3MnK·1.5thf] 1 and ion-separated [(η2-Cp)3Mn]2[Mg(thf)6] ·2thf 2 are obtained from reactions of CpK and Cp2Mg, respectively, with manganocene, Cp2Mn; they are the first complexes to be structurally characterised containing the [Cp3Mn] anion.

Back to tab navigation

Supplementary files

Article information


Submitted
17 Jul 2001
Accepted
21 Aug 2001
First published
28 Sep 2001

Chem. Commun., 2001, 1956-1957
Article type
Communication

The first observation of the [Cp3Mn] anion; structures of hexagonal [(η2-Cp)3MnK·1.5thf] and ion-separated [(η2-Cp)3Mn]2[Mg(thf)6] ·2thf

A. D. Bond, R. A. Layfield, J. A. MacAllister, M. McPartlin, J. M. Rawson and D. S. Wright, Chem. Commun., 2001, 1956
DOI: 10.1039/B106366A

Social activity

Search articles by author

Spotlight

Advertisements