The first structurally characterised homoleptic organovanadium(iii) compoundDedicated to Professor Dr Rafael Usón on the occasion of his 75th birthday.
Abstract
The homoleptic, tetrahedral, paramagnetic d2 species [NBu4][VIII(C6Cl5)4] 1 has been obtained and characterised by analytical, spectroscopic and X-ray diffraction methods.