Issue 22, 2001
From the journal:

Chemical Communications

Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(ii) clusters as subunitsElectronic supplementary information (ESI) available: the theoretical expressions of the intra-/inter-molecular magnetic interactions, two-dimensional view of 1, temperature dependence of ac magnetic susceptibility and field dependence of magnetization at 1.97 K. See http://www.rsc.org/suppdata/cc/b1/b106314f/

Hong-Ji Chen,ab   Zong-Wan Mao,a   Song Gao*c  and  Xiao-Ming Chen*a  

* Corresponding authors

a School of Chemistry & Chemical Engineering, Zhongshan University, Guangzhou, China.
E-mail: cescxm@zsu.edu.cn

b Department of Chemistry, Jinan University, Guangzhou, China

c State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China.
E-mail: gaosong@pku.edu.cn

Abstract

The crystal structure of the coordination polymer [Mn3(N3)2(nta)4(H2O)2]n (nta = nicotinate) consists of trinuclear subunits bridged by mixed μ-1,1-azide and μ-carboxylate-O,O groups, which are linked by μ3-nta-N,O,O ligands into a three-dimensional network exhibiting ferrimagnetic-like ordering.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B106314F
Article type
Communication
Submitted
16 Jul 2001
Accepted
11 Sep 2001
First published
25 Oct 2001

Chem. Commun., 2001, 2320-2321

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Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(II) clusters as subunits

H. Chen, Z. Mao, S. Gao and X. Chen, Chem. Commun., 2001, 2320 DOI: 10.1039/B106314F

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