Issue 16, 2001
From the journal:

Chemical Communications

The first molecular charge transfer salt containing proton channels

Samina Rashid,a   Scott S. Turner,a   Peter Day,*a   Mark E. Light,b   Michael B. Hursthouse,b   Steven Firthc  and  Robin J. H. Clarkc  

* Corresponding authors

a Davy Faraday Research Laboratory, The Royal Institution of Great Britain, 21 Albemarle Street, London, UK
E-mail: pday@ri.ac.uk

b Department of Chemistry, University of Southampton, Southampton, UK

c Chemistry Department, University College London, 20 Gordon Street, London, UK

Abstract

We report the first molecular charge transfer salt containing channels of H3O+/H2O within its lattice; it is formulated β″-(BEDT-TTF)4[(H3O)Cr(C2O 4)3]2[(H3O)2(18-cro wn-6)]·5H2O [BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene], deduced from the crystal structure and C[double bond, length half m-dash]C and C–S bond lengths and Raman stretching frequencies.

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Article information

DOI
https://doi.org/10.1039/B103877J
Article type
Communication
Submitted
30 Apr 2001
Accepted
27 Jun 2001
First published
20 Jul 2001

Chem. Commun., 2001, 1462-1463

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The first molecular charge transfer salt containing proton channels

S. Rashid, S. S. Turner, P. Day, M. E. Light, M. B. Hursthouse, S. Firth and R. J. H. Clark, Chem. Commun., 2001, 1462 DOI: 10.1039/B103877J

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